This book comprehensively discusses the basic principles and working mechanism of all kind of batteries towards clean energy storage devices. In addition, it focuses on the synthesis of various electrode materials with 1D architecture via electrospinning technique. This book will give a clear idea about recent synthetic strategy towards nanofibers and nanocomposites for alkali-ion storage applications. The reader could understand the formation mechanism of nanofibers and their potential application in the future energy storage system.