This book offers a complete and concise overview of the different strategies used to prepare microstructured surfaces employing information regarding surface instabilities and physical processes. Based upon the concept of the remarkably uniform layer of water vapor that is applied when one simply breathes onto a surface in cold temperatures, the book presents a comprehensive treatise addressing chemical and physical fundamentals, fabrication, and applications of the breath figures approach to surface wetting, coating, and modification (breath figures self-assembly) of various materials. The main topics of the book are divided into six parts: the control of surface properties in polymer blends; block copolymer design with the aim of providing order at different lengths; combination of block copolymer blends with the breath figures (BFs); dynamic templating; the breath figures method; biorecognition; and alternative approaches for surface structuring and functionalization.