This book constitutes the proceedings of the 16th International Conference on Coordination Models and Languages, COORDINATION 2014, held in Berlin, Germany, in June 2014. The 12 papers included in this volume were carefully reviewed and selected from 31 submissions. They deal with topics such as programming abstractions and languages, coordination models and paradigms, applied software engineering principles, specification and verification, foundations and types, distributed middleware architectures, multicore programming, collaborative adaptive systems, and coordination related use cases.