The authors describe how sustainable textile fibers from crops such as quinoa, grass, hops, corn and wheat stems, etc. have recently begun to generate great interest. The structure-property relationships of such non-conventional cellulose fibers are studied in this brief, as are their sorption and surface properties which are of primary importance. A systematic review of each fiber's properties is given, the emphasis is placed on the water sorption capacity, the fiber's surface potential, and fibrillation properties.